TRICYCLOHEXYLPHOSPHINE[1,3-BIS(2,4,6-TRIMETHYLPHENYL)IMIDAZOL-2-YLIDENE][3-PHENYL-1H-INDEN-1-YLIDENE]RUTHENIUM (II) DICHLORIDE - Names and Identifiers
Name | Dichloro[1,3-dihydro-1,3-bis(2,4,6-trimethylphenyl)-2H-imidazol-2-ylidene](3-phenyl-1H-inden-1-ylidene)(tricyclohexylphosphine)ruthenium
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Synonyms | (1,3-bis-(2,4,6-trimethylphenyl)imidazol-2-ylidene)(tricyclohexylphosphine)(3-phenylinden-1-ylidene)ruthenium(IV)dichloride TRICYCLOHEXYLPHOSPHINE [1,3-BIS(2,4,6-TRIMETHYLPHENYL)IMIDAZOL-2-YLIDENE][3-PHENYL-1H-INDEN-1-YLIDENE] RUTHENIUM (II) DICHLOR TRICYCLOHEXYLPHOSPHINE[1,3-BIS(2,4,6-TRIMETHYLPHENYL)IMIDAZOL-2-YLIDENE][3-PHENYL-1H-INDEN-1-YLIDENE]RUTHENIUM (II) DICHLORIDE Tricyclohexylphosphine [1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene][3-phenyl-1H-inden-1-ylidene] ruthenium (II) dichloride Dichloro[1,3-dihydro-1,3-bis(2,4,6-trimethylphenyl)-2H-imidazol-2-ylidene](3-phenyl-1H-inden-1-ylidene)(tricyclohexylphosphine)ruthenium
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CAS | 254972-49-1
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InChI | InChI=1S/C21H24N2.C18H33P.C15H10.2ClH.Ru/c1-14-9-16(3)20(17(4)10-14)22-7-8-23(13-22)21-18(5)11-15(2)12-19(21)6;1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2-6-12(7-3-1)15-11-10-13-8-4-5-9-14(13)15;;;/h7-12H,1-6H3;16-18H,1-15H2;1-9,11H;2*1H;/q;;;;;+2/p-2 |
TRICYCLOHEXYLPHOSPHINE[1,3-BIS(2,4,6-TRIMETHYLPHENYL)IMIDAZOL-2-YLIDENE][3-PHENYL-1H-INDEN-1-YLIDENE]RUTHENIUM (II) DICHLORIDE - Physico-chemical Properties
Molecular Formula | C54H67Cl2N2PRu
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Molar Mass | 947.07 |
Appearance | Powder |
Color | orange to brown |
Storage Condition | Room Temprature |
TRICYCLOHEXYLPHOSPHINE[1,3-BIS(2,4,6-TRIMETHYLPHENYL)IMIDAZOL-2-YLIDENE][3-PHENYL-1H-INDEN-1-YLIDENE]RUTHENIUM (II) DICHLORIDE - Risk and Safety
Risk Codes | 36/37/38 - Irritating to eyes, respiratory system and skin.
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Safety Description | S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection.
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TRICYCLOHEXYLPHOSPHINE[1,3-BIS(2,4,6-TRIMETHYLPHENYL)IMIDAZOL-2-YLIDENE][3-PHENYL-1H-INDEN-1-YLIDENE]RUTHENIUM (II) DICHLORIDE - Introduction
Dichloro[1,3-dihydro-1,3-bis(2,4,6-trimethylphenyl)-2H-imidazol-2-ylidene](tricyclohexylphosphine) ruum is a complex organometallic complex with the chemical formula C72H83Cl2N3P2Ru. The following is a description of its nature, use, preparation and safety information:
Nature:
1. Appearance: A yellow to orange solid.
2. Solubility: soluble in organic solvents such as dichloromethane, ether, insoluble in water.
3. Melting Point: about 150-180 ° C.
Use:
1. Catalyst: Dichloro[1,3-dihydro-1,3-bis(2,4,6-trimethylphenyl)-2H-imidazol-2-ylidene](phenyl) (tricyclohexylphosphate) ruthenium is an important metal organic catalyst, it can be widely used in organic reactions, such as cross-coupling reaction, asymmetric catalytic reaction and so on.
2. Organic synthesis intermediate: It can also be used as an intermediate for the synthesis of other organic compounds, such as metal organic frameworks.
Method:
The preparation of Dichloro[1,3-dihydro-1,3-bis(2,4,6-trimethylphenyl)-2H-imidazol-2-ylidene](tricyclohexylphosphate) ruthenium usually requires a series of steps, need more professional organic synthesis technology. The specific preparation method can refer to the relevant chemical literature.
Safety Information:
1. Dichloro[1,3-dihydro-1,3-bis(2,4,6-trimethylphenyl)-2H-imidazol-2-ylidene](tricyclohexylphosphine)ruthenium has no obvious toxicity under general conditions, however, care should be taken to avoid contact with skin and eyes.
2. General laboratory safety practices should be followed during use and preparation, including wearing appropriate personal protective equipment and operating in well-ventilated conditions.
The information presented above is for reference only. When using and handling this compound, you should carefully read the relevant literature and safety instructions and follow the guidance of professionals.
Last Update:2024-04-10 22:29:15